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31.
34S/32S ratios have been measured in a suite of samples from the stratabound, volcanogenic massive sulphide deposit at Woodlawn, N.S.W. 34S values for the sulphides vary as follows: in the ore horizon, pyrite +6.7 to +9.2%. (mean +8.1‰), sphalerite +5.2 to +8.6‰. (mean +6.9‰), chalcopyrite +6.4 to +7.0‰ (mean +6.7‰) and galena +2.8 to +5.5‰ (mean +4.4‰); in the vein mineralization, the host volcanics—pyrite +8.7 to +11.4%. (mean +9.8‰), sphalerite +7.8 to + 10.3‰ (mean +9.2‰), chalcopyrite; +8.8 to +10.1‰ (mean +9.2‰) and galena +6.9 to +7.2‰ (mean +7.1‰). Barite from the upper ore horizon levels has an isotopic composition of +30.0‰, consistent with its having originated from Silurian ocean sulphate. The general order of 34S enrichment in the sulphides is pyrite > chalcopyrite ~ sphalerite > galena. Isotopic fractionations in the systems galena/sphalerite/pyrite and chalcopyrite/pyrite indicate an equilibration temperature of 275–300°C. This temperature is considered to represent that of sulphide deposition. 相似文献
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Arthur Ayres Neto Vanessa Alves da Costa Clara Pinto Ferreira Maia Porto Thais Cristina Vargas Garrido Jean-Pierre Hermand 《Marine Georesources & Geotechnology》2020,38(4):437-449
AbstractMarine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource. 相似文献
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Seismic velocities ( V p and V s ) of compressional (P-) and shear (S-) waves are important parameters for the characterization of marine sediments with respect to their sedimentological and geotechnical properties. P- and S-wave velocity data of near-surface marine sediments (upper 9 m) of the continental slope of the Barents Sea are analysed and correlated to sedimentological and geotechnical properties. The results show that the S-wave velocity is much more sensitive to changes in lithology and mechanical properties than the P-wave velocity, which is characterized by a narrow range of values. The correlation coefficients between S-wave velocity and silt and clay content, wet bulk density, porosity, water content and shear strength are higher than 0.5 while the correlation coefficients of P-wave velocity and the same parameters are always lower than 0.4. Although the relationship between V s and clay content has been widely described, the data show that V s is better correlated with silt content than with clay content for the sediments of the area investigated. However, they show different trends. While V s increases with increasing clay content, it decreases with increasing silt content. 相似文献